贵长猕猴桃皮HPLC指纹图谱及抗氧化谱效关系研究

目的:研究贵长猕猴桃皮HPLC指纹图谱与抗氧化活性的关系。方法:采用高效液相色谱法建立10批不同来源地贵长猕猴桃皮的指纹图谱,采用SPSS 13.0进行样品聚类分析和主成分分析;并通过DPPH和ABTS法测定其抗氧化活性,以EC50与共有峰峰面积数据为基础,应用皮尔逊相关分析法和逐步回归分析法研究谱效关系。结果:建立了10批贵长猕猴桃皮HPLC指纹图谱,确定了14个共有峰,相似度均>0.90。采用对照品比对方法指认了其中6个峰:2号峰没食子酸,5号峰原儿茶酸,9号峰表儿茶素,10号峰二氢槲皮素,11号峰4-香豆酸,12号峰落新妇苷,样本可聚为3类。皮尔逊相关分析与逐步回归分析结果显示:5号峰(原儿茶酸)和9号峰(表儿茶素)峰面积变化与贵长猕猴桃皮抗氧化活性呈显著正相关,对其抗氧化活性贡献度较大。结论:贵长猕猴桃皮具有较高的体外抗氧化活性,抗氧化活性的物质基础初步确定为贵长猕猴桃皮开发利用、质量评价提供依据。     

Prediction of mode I fracture toughness of rock using linear multiple regression and gene expression programming

Prediction of mode I fracture toughness (K_IC) of rock is of significant importance in rock engineering analyses. In this study, linear multiple regression (LMR) and gene expression programming (GEP) methods were used to provide a reliable relationship to determine mode I fracture toughness of rock. The presented model was developed based on 60 datasets taken from the previous literature. To predict fracture parameters, three mechanical parameters of rock mass including uniaxial compressive strength (UCS), Brazilian tensile strength (BTS), and elastic modulus (E) have been selected as the input parameters. A cluster of data was collected and divided into two random groups of training and testing datasets. Then, different statistical linear and artificial intelligence based nonlinear analyses were conducted on the training data to provide a reliable prediction model of K_IC. These two predictive methods were then evaluated based on the testing data. To evaluate the efficiency of the proposed models for predicting the mode I fracture toughness of rock, various statistical indices including coefficient of determination (R²), root mean square error (RMSE), and mean absolute error (MAE) were utilized herein. In the case of testing datasets, the values of R², RMSE, and MAE for the GEP model were 0.87, 0.188, and 0.156, respectively, while they were 0.74, 0.473, and 0.223, respectively, for the LMR model. The results indicated that the selected GEP model delivered superior performance with a higher R² value and lower errors.     

A rapid method to quantify casein in fluid milk by front-face fluorescence spectroscopy combined with chemometrics

Casein in fluid milk determines cheese yield and affects cheese quality. Traditional methods of measuring casein in milk involve lengthy sample preparations with labor-intensive nitrogen-based protein quantifications. The objective of this study was to quantify casein in fluid milk with different casein-to-crude-protein ratios using front-face fluorescence spectroscopy (FFFS) and chemometrics. We constructed calibration samples by mixing microfiltration and ultrafiltration retentate and permeate in different ratios to obtain different casein concentrations and casein-to-crude-protein ratios. We developed partial least squares regression and elastic net regression models for casein prediction in fluid milk using FFFS tryptophan emission spectra and reference casein contents. We used a set of 20 validation samples (including raw, skim, and ultrafiltered milk) to optimize and validate model performance. We externally tested another independent set of 20 test samples (including raw, skim, and ultrafiltered milk) by root mean square error of prediction (RMSEP), residual prediction deviation (RPD), and relative prediction error (RPE). The RMSEP for casein content quantification in raw, skim, and ultrafiltered milk ranged from 0.12 to 0.13%, and the RPD ranged from 3.2 to 3.4. The externally validated error of prediction was comparable to the existing rapid method and showed practical model performance for quality-control purposes. This FFFS-based method can be implemented as a routine quality-control tool in the dairy industry, providing rapid quantification of casein content in fluid milk intended for cheese manufacturing.     

液层Pr比值对环形双液层热毛细对流的影响

为了解双层流体系统上液层流体与下液层流体普朗特数(Pr)对热毛细对流的影响,通过线性稳定性分析,确定了上液层流体与下液层流体Pr比值从0.164～5.417时环形双层流体热毛细对流失稳的临界条件,预测了它们的4种流动失稳型式,即轮辐状的几乎占据了整个液层的"轮辐波"、轮辐状的热流体波与同波数共同旋向的靠热壁处流胞、径向流动的三维稳态流动、靠热壁处的短小的"边沿波"。结果表明:随着上、下液层Pr比值的增大,环形双液层流体的流动稳定性以上、下液层Pr比值0.750为分界线呈分段上升趋势。上、下液层Pr比值约为0.750时,双液层流体的稳定性最差,此时易出现流动分岔现象。为了获得更好的系统流动稳定性、提高生长晶体的质量,在选择双液层工质对时,应选择上、下液层Pr比值较大的工质对。     

A comparative assessment of local municipal food policy integration in the Netherlands

ABSTRACT

Local governments around the world increasingly engage in food governance, aiming to address food system challenges such as obesity, food waste, or food insecurity. However, the extent to which municipalities have actually integrated food across their policies remains unknown. This study addresses this question by conducting a medium-n systematic content analysis of local food policy outputs of 31 Dutch municipalities. Policy outputs were coded for the food goals and instruments adopted by local governments. Our analysis shows that most municipalities integrate food to a limited extent only, predominantly addressing health and local food production or consumption. Furthermore, municipalities seem hesitant to use coercive instruments and predominantly employ informative and organizational instruments. Nonetheless, a small number of municipalities have developed more holistic approaches to address food challenges. These cities may prove to be a leading group in the development of system-based approaches in Dutch local food policy.     

Influences of chitosan on freeze–thaw stability of Arenga pinnata starch

This study aims to investigate chitosan (CS) with five different molecular weight (Mw) on freeze–thaw stability of Arenga pinnata starch (APS) gel subjected to five freeze–thaw cycles (FTC). The syneresis of APS gels was reduced by adding CS and the APS gel with high Mw CS had lower syneresis duo to a higher water holding capacity (P < 0.05). The addition of CS significantly decreased the hardness and molecular ordered structure of APS gel. In addition, CS could improve the microstructural stability. The results suggested that CS could effectively improve the freeze–thaw stability of APS gel, and CS with higher Mw might have more practical utility to improve stability of APS gel.     

Structural and operational management of Turkish airports: a bootstrap data envelopment analysis of efficiency

This paper explores the structural and operational dimensions of the efficiencies of airports. The two-stage procedure is suggested to assess the efficiencies of airports in this study. In the first-stage, Classification and Regression Tree, which is one of the machine-learning approaches used to divide the airports into homogeneous and thus comparable sub-groups. In the second stage, the bootstrap data envelopment analysis approach obtains more precise structural and operational efficiency scores. To illustrate the proposed framework use, we applied it to a real case associated with Turkish airports. The results demonstrate that this framework presents a more comprehensive assessment of airport performance rather than conventional data envelopment analysis models. Moreover, it provides to show the deficiencies of the structural and operational management of airports. The findings can help anywhere airport authorities as well as Turkish airport authorities.     

Full and reduced-order H∞ filtering of Takagi–Sugeno fuzzy time-varying delay systems: Input–output approach

This article addresses the issue of delay-dependent H_∞ filtering design for TakagiŮSugeno fuzzy time-varying delay systems using the input–output approach. A three-term approximation model has been used to transform the original system into two interconnected subsystems. Since the nonquadratic Lyapunov–Krasovskii functional requires to deal with the membership function's (MF) time derivative, upper-bound inequalities have been added to the obtained conditions. Based on the scaled small gain theorem, nonquadratic Lyapunov–Krasovskii functional approach and considering the bounds of the MF time-derivative, the H_∞ full- and reduced-order filters are designed and then formulated in terms of linear matrix inequalities. Finally, illustrative examples are presented to demonstrate the validity of the proposed methods.     

航班恢复问题的迭代局部搜索算法

在恶劣天气和机械故障等原因造成航班不能按照原计划执行时，航空公司需要采取相应的措施对航班进行恢复。本文基于经典的资源指派模型，综合考虑了调整时间、换机、联程拉直、取消航班和调机5种恢复策略，提出一种以最小化加权成本为优化目标的航班恢复模型，并设计一种迭代局部搜索算法。首先用构造-修复启发式方法构造可行解，然后从该初始解出发，在飞机路线对的邻域中进行局部搜索。当陷入局部最优后，对解进行扰动，然后从扰动后的解重新出发进行局部搜索。为了提高搜索效率，同时降低陷入局部最优解的概率，局部搜索过程采用模拟退火算法。实例结果表明，本文提出的模型及算法能够在短时间内对受到影响的大规模航班计划进行恢复。